Title | Paralava and clinker from the Canadian Arctic: a record of combustion metamorphism dating back to the late Miocene |
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Author | Reinhardt, L; Estrada, S; Koglin, N; Piepjohn, K; Galloway, J M |
Source | Canadian Journal of Earth Sciences 2023 p. 1-33, https://doi.org/10.1139/cjes-2022-0142 Open Access |
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Year | 2023 |
Alt Series | Natural Resources Canada, Contribution Series 20220094 |
Publisher | Canadian Science Publishing |
Document | serial |
Lang. | English |
Media | paper; digital; on-line |
File format | pdf; html |
Province | Nunavut |
NTS | 49E |
Area | Canadian Arctic; Ellesmere Island; Banks Island; Mackenzie Delta |
Lat/Long WENS | -84.0000 -80.0000 79.0000 78.0000 |
Subjects | general geology; geochemistry; metamorphism; Cenozoic |
Illustrations | location maps; diagrams; photographs; tables; graphs; charts |
Program | GEM-GeoNorth: Geo-mapping for Energy and Minerals GEM Program Coordination |
Released | 2023 05 26 |
Abstract | Outcrops with conspicuous reddish to yellow-colored clinker, blackish paralava, and blends of both with a breccia-like appearance occur across the Canadian Arctic. We examined such rocks on Ellesmere
Island, Banks Island, and the Mackenzie Delta area. These rocks are a product from natural combustion of bituminous shale and low-rank coal seams in Cretaceous and Paleogene host sedimentary rocks, respectively. The main mineral phases of clinker and
silicate paralava samples are comprised of quartz + hematite ± feldspars ± cristobalite (or tridymite) ± cordierite–sekaninaite ± clinopyroxene ± sillimanite ± glass. Slag-like iron oxide paralava (74–95 wt.% total Fe2O3) consisting of hematite ±
magnetite ± clinopyroxene occur in Paleogene host sedimentary rocks, rich in siderite concretions. The whole-rock geochemical composition of clinker and silicate paralava shows similarities for samples from the same outcrop. Regional and local
specific elemental enrichments are mainly inherited from the sedimentary protoliths, which are characterized by volcanogenic input (Paleocene sedimentary rocks) or oxygen-depleted depositional conditions (Upper Cretaceous bituminous sedimentary
rocks). Spontaneous combustion could take place when the organic-rich sedimentary rocks become exposed to atmospheric oxygen. This process has occurred at least since the Messinian stage (Miocene) on Ellesmere Island (6.1 ± 0.2 Ma; 40Ar/39Ar
incremental heating dating on whole-rock paralava) and continues until now. An active combustion process on scree from a coal seam and clastic Eureka Sound Group sedimentary rocks was observed on Ellesmere Island. |
Summary | (Plain Language Summary, not published) In the Canadian Arctic, Upper Cretaceous and Paleogene rocks are known to spontaneous combust. The products of these combustions are known as paralava or
clinker. Samples of paralava and clinker were collected from several locations across the Canadian Arctic and Mackenzie Delta region and were analyzed for their geochemical composition and age. The mineralogy of the paralava and clinker are
reported. |
GEOSCAN ID | 330148 |
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