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TitleExtensive jarosite deposits formed through auto-combustion and weathering of pyritiferous mudstone, Smoking Hills (Ingniryuat), Northwest Territories, Canadian Arctic - a potential Mars analogue
 
AuthorGrasby, S EORCID logo; Percival, J BORCID logo; Bilot, I; Ardakani, O HORCID logo; Smith, I RORCID logo; Galloway, JORCID logo; Bringué, MORCID logo; McLoughlin-Coleman, TORCID logo
SourceChemical Geology vol. 587, 120634, 2021 p. 1-17, https://doi.org/10.1016/j.chemgeo.2021.120634 Open Access logo Open Access
Image
Year2021
Alt SeriesNatural Resources Canada, Contribution Series 20210377
PublisherElsevier
Documentserial
Lang.English
Mediapaper; digital; on-line
File formatpdf; html
ProvinceNorthwest Territories
NTS97C/05; 97C/06; 97C/11; 97C/12; 97C/13; 97C/14
AreaIngniryuat; Smoking Hills
Lat/Long WENS-127.7500 -126.0333 69.8833 69.3167
Subjectsmineralogy; geochemistry; extraterrestrial geology; Science and Technology; Nature and Environment; jarosite; metals; sulphates; bedrock geology; lithology; sedimentary rocks; mudstones; pyrite; weathering; paleoenvironment; marine environments; continental margins; acidity; salinity; precipitation; phyllosilicates; depositional history; Smoking Hills Formation; Phanerozoic; Mesozoic; Cretaceous
Illustrationstables; location maps; geoscientific sketch maps; photographs; profiles; plots; photomicrographs
ProgramGEM-GeoNorth: Geo-mapping for Energy and Minerals GEM Program Coordination
Released2021 11 16
AbstractJarosite and other metal sulphates are common on Mars and are interpreted to have formed in an extreme acidic saline aqueous environment, similar to modern Earth analogues where jarosite precipitates. We examined an alternative Earth analogue, at the Smoking Hills (known as Ingniryuat by Inuvialuit), Northwest Territories, Arctic Canada. The Smoking Hills are characterised by auto-combusting pyritic mudstones of the Smoking Hills Formation in a polar desert. The Smoking Hills Formation was deposited in an outer shelf to slope marine environment, during a Late Cretaceous Ocean Anoxic Event. Oxidative weathering of this unit creates extensive jarosite-rich deposits, and banded jarosite- and phyllosilicate-rich mudstones, similar to those observed on Mars. Slumping of these mudstones exposes large masses to atmospheric oxygen leading to generation of high temperatures (sufficient to produce paralavas) through pyrite oxidation, and the subsequent formation of a diverse suite of hydrated metal-sulphate minerals. Weathered combustion sites are characterised by a simpler jarosite-rich mineralogy along with thermally-altered mudstone. Away from sites of auto-combustion (bocannes), pyrite-rich layers within the mudstone oxidise to jarosite, creating a yellow-banded appearance in outcrops. These jarosite-rich layers, similar to those observed interbedded in mudstones on Mars, reflect post depositional oxidation processes - not acidic conditions during the time of deposition. As such, this could reflect a more habitable environment than is commonly interpreted for Mars.
Summary(Plain Language Summary, not published)
Naturally burning shales were examined in the Smoking Hills area. A complex array of rare minerals including jarosite are found at the site that are similar to those found on Mars and used to interpret Mars as having standing water, but that which was highly acidic, being inhospitable to life. The Smoking Hills area has similar exposures to those at Mars but we are able to show that the jarosite deposits there are formed by weathering of pyrite rich layers in the shale. This means that the deposits on Mars could reflect much more habitable environments than originally thought.
GEOSCAN ID329151

 
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