| Abstract | Scheelite (CaWO4) collected from 37 different ore-deposit settings (orogenic, sediment- and greenstone-hosted, skarn, porphyry, greisen, volcanogenic massive sulfide, breccia, and polymetallic deposits)
globally was examined and evaluated using a combination of cathodoluminescence (CL), SEM-EDS, LA-ICP-MS, and delta O-18 analytical methods. These data provided the basis to assess whether the crystal-chemistry of scheelite could be used to
distinguish between differing environments of formation. The results show: (1) scheelite can record very complex growth histories based on CL images and elemental mapping; (2) predominant elemental substitutions involve As5+ or Mo6+ <-> W6+ and Sr2+
or REE3+ <-> Ca2+; (3) highly variable trends for the REEs that vary in terms of Sigma REEs (below detection to 10(4) range in CN values), the degree and nature of fractionation (i.e., flat, convex, concave), and the nature of Eu-N values, which are
both positive and negative, with Eu anomalies (Eu-A) ranging from,<0.1 to >20-30; and (4) delta O-18 values varying from -4.6 to +12.7 parts per thousand, which apparently do not relate to a deposit-specific fluid signature (delta O-18(H2O)). The
variability in REE patterns suggests that many factors affect both Sigma REE and incorporation, hence the observed fractionation, into scheelite (e.g., fluid chemistry, coprecipitation of other REE-bearing minerals). Substitutions involving Mo and As
are of particular relevance, as both elements are redox sensitive and their enrichment is reflected in ore-deposit settings such that reduced orogenic-type Au-W deposits are As and Mo depleted in contrast to the more oxidized intrusion-related
deposits where Mo is enriched (>100 ppm). Similarly, both the EuA values and Sr are relatively enriched in orogenic settings versus intrusion-related settings. These observed chemical differences for Sr, Mo, and Eu-A in scheelite from different
deposit settings were used to construct the first ever discriminant diagram for scheelite, which is summarized in a plot of Eu-A versus Sr/Mo, which successfully discriminates the samples used in this study. Thus, the crystal-chemistry of scheelite
is shown to be both a strong indicator of ore-forming conditions and an ore-deposit discriminator. |