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TitleDebate on some algorithms relating concentration to intensity in XRF spectrometry
 
AuthorRousseau, R M
SourceRigaku Journal vol. 19, no. 1, 2002 p. 25-34
LinksOnline - En ligne
Year2002
Alt SeriesEarth Sciences Sector, Contribution Series 20060240
Documentserial
Lang.English
Mediapaper; on-line; digital
File formatpdf
Subjectsmathematical and computational geology; x-ray fluorescence; x-ray fluorescence analyses; spectrometric analyses; concentration; Fundamental Algorithm; algorithms; spectrometry; intensity
Illustrationsformulae; graphs
AbstractWillis and Lachance [9] debate the pertinence of a recent study done by Rousseau [2] of three "popular expressions" relating concentration to intensity in X-ray fluorescence (XRF) analysis. It should be pointed out that Willis and Lachance debate only the Lachance identity (Eqn 1) and its associated "new" Lachance-Traill algorithm (Eqn 2) and ignore the two other expressions, namely Claisse-Quintin and Broil-Tertian algorithms [2]. They also continue to ignore the fundamental character of the algorithm proposed by Rousseau [1]. The author would like to thank Willis and Lachance to give him the opportunity to debate six of his arguments in a rational and objective way. As a result the XRF analysts will be able to select the most reliable analytical methods, for getting the most accurate results, with full knowledge of the facts. Their choice of a method will not be based only on the reputation of its author... Finally the author discusses the validity of the four last conclusions that were reached by Willis and Lachance.
GEOSCAN ID222741

 
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